Abstract The van’t Hoff method is a standard approach for determining reaction enthalpies and entropies, e.g., in the thermochemical reduction of oxides, which is an important process for solar thermochemical fuels and numerous other applications. However, by analyzing the oxygen partial pressure pO2, e.g., as measured by thermogravimetric analysis (TGA), this method convolutes the properties …
Published at Journal of the American Chemical Society – Chemical Potential Analysis as an Alternative to the van’t Hoff Method: Hypothetical Limits of Solar Thermochemical Hydrogen
