Abstract Hydrogen holds promise as a clean energy carrier, but its industrial utilization is currently constrained by the challenges of green production and efficient cross-regional delivery. To this end, a novel integrated hydrogen energy system considering the solar-driven biomass gasification and liquid organic hydrogen storage was developed in this work. In the newly developed system, …
Published at Journal of the American Chemical Society – Chemical Potential Analysis as an Alternative to the van’t Hoff Method: Hypothetical Limits of Solar Thermochemical Hydrogen
Abstract The van’t Hoff method is a standard approach for determining reaction enthalpies and entropies, e.g., in the thermochemical reduction of oxides, which is an important process for solar thermochemical fuels and numerous other applications. However, by analyzing the oxygen partial pressure pO2, e.g., as measured by thermogravimetric analysis (TGA), this method convolutes the properties …